Aug. 17, 2018
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NIF Reveals How Hydrogen Becomes Metallic in Giant Planets

By Breanna Bishop

Swirling dense metallic hydrogen dominates the interiors of Jupiter, Saturn and many extra-solar planets. Building precise models of these giant planets requires an accurate description of the transition of pressurized hydrogen into this metallic substance—a long-standing scientific challenge.

In a paper published on Aug. 17 by Science, a research team led by LLNL scientists describes optical measurements of the insulator-to-metal transition in fluid hydrogen, resolving discrepancies in previous experiments and establishing new benchmarks for calculations used to construct planetary models.

The multi-institution team included researchers from the French Alternative Energies and Atomic Energy Commission (CEA), the University of Edinburgh, the University of Rochester, Carnegie Institution of Washington, the University of California, Berkeley, and The George Washington University.

Decades of research have revealed that high temperatures combined with high pressure progressively transform dense fluid hydrogen into an electrically conducting fluid. Surprisingly, computer simulations suggest that below 2,000 Kelvin (K), increasing the pressure could trigger a sudden insulator-to-metal transition. How much pressure is needed has been uncertain, because various theoretical models and numerical techniques experiments provide very different predictions.

"Our challenge was to design an experiment that could dynamically compress a sample of fluid hydrogen to several million atmospheres and do it gently enough (without a strong shock) that it remained cool, or below 2,000 K, to see which of the theoretical models was right," said LLNL physicist Peter Celliers, lead author of the paper.

"We performed a series of experiments that provide a clear signature of the metallization transition," Celliers said, "and from the data we have identified at what conditions in pressure-temperature space the transition is occurring. The results clearly show which models are right, which are not and a couple that are close. Choosing the right model is important for planetary scientists who are trying to predict the internal structure of Jupiter and Saturn."

In addition, understanding the behavior of hydrogen under pressure is an important facet of the National Nuclear Security Administration (NNSA)’s efforts in inertial confinement fusion. Research in the areas of extreme temperatures, pressures, and densities also contributes to NNSA’s Stockpile Stewardship Program that helps ensure that the current and future nuclear stockpile is safe and reliable.

A series of five experiments was conducted at NIF, the world’s largest and highest-energy laser. First, the researchers condensed a thin layer of cryogenic liquid deuterium (a heavy isotope of hydrogen) by cooling to 21 K (-422 degrees Fahrenheit). They created a sequence of reverberating shockwaves using 168 of NIF’s 192 laser beams, compressing the deuterium fluid to 600 GPa (6 million atmospheres, nearly twice the pressure at the center of the Earth) while keeping the temperature between 1,000 and 2,000 K.

The sample started completely transparent, but as the pressure rose, it became opaque before transforming into a shiny metal whose high optical reflectivity is a signature for high electrical conductivity. An optical diagnostic instrument called VISAR recorded the reflectivity of the sample and the Doppler shift in the reflected light beam to determine the pressure in the sample.

Gene Frieders Inspects the VISAR
Responsible system engineer Gene Frieders inspects the VISAR (Velocity Interferometer System for Any Reflector) diagnostic. The VISAR instrument is an ultrafast optical diagnostic that uses a pulsed laser and interferometry to measure the velocity of the shock waves and characterize the optical properties of the fluid hydrogen during the insulator-to-metal transition. Credit: Jason Laurea

"It’s like squeezing air and turning it into a shiny, light version of liquid mercury," said Raymond Jeanloz, professor of astronomy and earth and planetary science at the University of California, Berkeley and a co-author of the publication. "Although exotic at Earth’s surface," Jeanloz said, "metallic hydrogen is the main material inside most giant planets and stars."

According to Celliers, the final results are a determination of the pressure and temperature at which the metallization occurs to compare with theoretical models. "From careful examination of the signals," he said, " we also learned new information about the refractive index and the absorption coefficient in the sample."

"These results are a true experimental tour de force," added LLNL physicist Marius Millot, a co-author of the paper, "and are particularly important because they provide a very stringent test on the different varieties of numerical simulations that one can use to predict the properties of planetary constituents at high pressure—necessary to model the internal structure and evolutionary processes of Jupiter and Saturn.

Graph Showing Estimated Temperature-pressure Paths
Estimated temperature-pressure paths for the five NIF experiments. The upper and lower bounds are estimated from the spread among the equation-of-state models; the solid curves are mean values.

"Now, thanks to the excellent performance and reproducibility of NIF and exquisite quality of data," he said, "our results bring new insight and verify predictions."

The research was conducted as part of NIF’s Discovery Science Program, which allocates experimental time to researchers conducting breakthrough experiments in a variety of fields. This collaboration has been awarded additional time and is in the process of planning new experiments. Looking ahead, the team hopes to detect new exotic stages of hydrogen by pushing into higher pressures while maintaining lower temperatures.

"Because it is made of just one electron and one proton," Millot noted, "understanding how the properties of hydrogen are modified by applying high pressures, which brings the atoms closer and closer to each other, is a great playground for condensed matter theoreticians.

"Hydrogen at high pressures and temperatures is the main constituent of gas giant planets and stars, so it is obviously important to study its properties if we want to understand where we come from, how the solar system was formed and evolved, etc," he said. "For example, because fluid convection of metallic hydrogen generates the magnetic field of these planets, our data will be helpful in interpreting the amazing data collected by the Juno and Cassini missions."

Celliers, Jeanloz, and Millot were joined by co-authors Dayne Fratanduono, Jon Eggert, Luc Peterson, Nathan Meezan, and Sebastien Le Pape of LLNL; Stephanie Brygoo and Paul Loubeyre of CEA; Stewart McWilliams of the University of Edinburgh; Alexander Goncharov of the Carnegie Institution of Washington; Ryan Rygg and Rip Collins of the University of Rochester; and Russell Hemley of The George Washington University.

The research was supported in part by the Laboratory Directed Research and Development program and the NIF team.